ELECTRICAL MATERIALS AND EQUIPMENT VOLUME: 15 |NUMBER: 1 |2017 |MARCH Experimental Enhancement for Electric Properties of Polyethylene Nanocomposites under Thermal Conditions Ahmed THABET1, Youssef MOBARAK1,2 1Nanotechnology Research Center, Faculty of Energy Engineering, Aswan University, 81528 Aswan, Egypt 2Department of Electrical Engineering, Faculty of Engineering Rabigh, King Abdulaziz University, 21589 Jeddah, Kingdom of Saudi Arabia [email protected],
[email protected] DOI: 10.15598/aeee.v15i1.1727 Abstract. Polymer properties can be experimentally tailored by adding small amounts of different nanoparticles for enhancing their mechanical, thermal and electrical properties. The work in this paper investigates enhancing the electric and dielectric properties of Low Density Polyethylene (LDPE), and High Density Polyethylene (HDPE) polymer materials with cheap nanoparticles. Certain percentages of clay and fumed silica nanoparticles are used to enhance electric and dielectric properties of polyethylene nanocomposites films. By using the Dielectric Spectroscopy; the electric and dielectric properties of each polyethylene nanocomposites have been measured with and without nanoparticles at various frequencies up to 1 kHz under different thermal conditions (20 ◦C and 60 ◦C). And so, we were successful in specifying the optimal nanoparticles types and their concentrations for the control of electric and dielectric characterization. Keywords Dielectric properties, electric properties, nanocomposite, nanoparticles, polyethylene, polymers. 1. Introduction Nanocomposites represent a very attractive route to upgrade and diversify properties of the polymers. Nano-filler-filled polymers might be differentiated from micro-filler-filled polymers and so the characteristics are reflected in their material properties [1]. In general, fillers are added to polymeric materials in order to enhance thermal and mechanical properties. Over the past few years there have been many researches on the effect of fillers on dielectric properties of polymers [2] and [3]. Polymer nanocomposites films have attracted wide interest for enhancing polymer properties and extending their utility in recent years. PolyEthylene (PE) is widely used as an insulating material for power cables. Electrical insulating polymers are usually modified with inorganic fillers to improve electrical, mechanical, thermal properties. Generally, inorganic fillers are dispersed non-uniformly in the polymer matrix, and the irregular interfaces are usually electrically weak spots. It is well known that the electrical properties of insulating polymer composites depend strongly on their microstructures. In particular, the size and shape of the fillers, the dispersion of the fillers, the filler-filler and filler-matrix interactions including interfacial strain, directly affect the electrical properties of composites [4], [5], [6], [7], [8], [9] and [10]. Nanoparticles/polymer composites are now interested for their specific electrical properties. It is recognized that the interfaces between the host dielectric and the nanometric particles can strongly influence the dielectric properties of the composite material as a whole. Since interfaces dominate dielectric situations at this level, nanodielectrics and interfaces become inextricable [11], [12], [13], [14], [15], [16] and [17]. As of now, work is underway to examine the physical properties of nanocomposites materials composed of nanoparticles of metals and their compounds stabilized within a polymeric dielectric matrix. It has been found that the dielectric properties have a close relationship with the interfacial behavior between the nanoparticles and the polymer matrix in such nanocomposites films [18], [19] and [20]. Nowadays, the effects of nanoparticles in many polymers have been enhanced electric and dielectric behaviour depending on the size, c 2017 ADVANCES IN ELECTRICAL AND ELECTRONIC ENGINEERING 55
ELECTRICAL MATERIALS AND EQUIPMENT VOLUME: 15 |NUMBER: 1 |2017 |MARCH structure, and concentration of the nanoparticles, as well as the type of polymeric matrix [21], [22], [23], [24], [25], [26], [27], [28], [29] and [30]. With a continual progress in polymer nanocomposites films, the main objective of this paper is studying the effects of nanoparticles on conductance and susceptance of insulating polyethylene nanocomposites films to achieve more cost-effective, energy-effective and hence environmentally better materials for the electrical insulation technology. Also, this research depicts the effects of types and concentrations of cheap nanoparticles on electrical properties of industrial polymer material. Our experimental results show the effects of clay and fumed silica nanoparticles on electric and dielectric properties of polyethylene under thermal conditions. 2. Experimental Setup 2.1. Nanoparticles Clay and fumed silica nanoparticles are cheap catalysts that change the properties of industrial materials with respect to physical manufacture process. 2.2. Polyethylene Base Matrix Polymer Polyethylene is a thermoplastic made from petroleum, unreactive at room temperatures, and with all but strong oxidizing agents, and some solvents causing swelling. It can withstand temperatures of 80 ◦C and 95 ◦C for a short time. This polymer is a commercial material that is used in the manufacturing of highvoltage industrial products. Polyethylene nanocomposites films have been manufactured by using melting polyethylene (LDPE and HDPE), then, mixing and penetrating nanoparticles inside the base matrix polyethylene by modern ultrasonic devices. SEM images for polyethylene nanocomposites films illustrate the penetration of nanoparticles inside lowdensity polyethylene and high-density polyethylene as shown in Fig. 1. And so, Tab. 1 depicts the measured electric and dielectric properties of polyethylene nanocomposites materials. 2.3. Electric Characterization Measurements Figure 2 shows HIOKI 3522-50 LCR Hi-tester device that measured characterization of nanocomposites insulation industrial materials, it has been used for (a) Clay/LDPE. (b) SiO2/LDPE. (c) Clay/HDPE. (d) SiO2/HDPE. Fig. 1: SEM images for polyethylene nanocomposite films. measuring electric and dielectric parameters of nanometric solid dielectric insulation specimens at various frequencies. Specification and accuracy of LCR Hitester device have been defined as follows, Power supply: 100, 120, 220 or 240 V (±10 %) AC (selectable), 50/60 Hz, and Frequency: DC, 1 MHz to 100 kHz, Display Screen: LCD with backlight / 99999 (full 5 digits), Basic Accuracy: Z: ±0.08 % rdg. θ:±0.05◦and External DC bias ±40 V max.(option) (3522-50 used alone ±10 V max./ using 9268 ±40 V max). SECTION POLICIES VOLUME: XX | NUMBER: X | 2015 | MONTH © 2015 ADVANCES IN ELECTRICAL AND ELECTRONIC ENGINEERING 2 inorganic filler to an elastomer will increase its stiffness, albeit at the expense of reduced elongation at break [1014]. As of now, work is underway to examine the physical properties of nanocomposite materials composed of nanoparticles and their compounds stabilized within a polymeric dielectric matrix. In recent years polymer nanocomposites have attracted wide interest with regard to enhancing polymer properties and extending their utility. It has been found that the dielectric properties have a close relationship with the interfacial behaviour between the fillers and the polymer matrix in such composites. The electric and optic properties of these materials have been demonstrated to be highly dependent on the size, structure, and concentration of the nanoparticles, as well as on the type of polymeric matrix [15-19]. Great expectations have been focused on effects and importance of costless nanoparticles [20-25]. However, it has been concerned in this paper about the effect of types of costless nanoparticles on the electrical properties of a polymeric nanocomposite. With a continual progress in polymer nanocomposites, this research depicts the effects of types and concentration of costless nanoparticles in electrical properties of industrial polymer material. All the experimental results of dielectric spectroscopy have been investigated and discussed to detect all nanoparticles effects on electrical properties of nanocomposite industrial material which fabricated; like High Density Polyethylene (HDPE) with various nanoparticles of clay and fumed silica. 2. Experimental Setup HIOKI 3522-50 LCR Hi-tester device measured electrical parameters of nanocomposite solid dielectric insulation specimens at various frequencies: |Z|, |Y|, θ, Rp (DCR), Rs (ESR, DCR),G, X, B, Cp, Cs, Lp, Ls, D (tan δ), and Q. Specification of LCR is Power supply: 100, 120, 220 or 240 V(±10%) AC (selectable), 50/60 Hz, Frequency: DC, 1 mHz to 100 kHz, Display Screen: LCD with backlight / 99999 (full 5 digits), Basic Accuracy: Z : ± 0.08% rdg. θ : ± 0.05˚, and External DC bias ± 40 V max.(option) (352250 used alone ± 10 V max./ using 9268 ± 40 V max.). Fig. 1: HIOKI 3522-50 LCR Hi-tester device. Finally, all dielectric properties for pure and nanocomposite industrial materials can be measured using HIOKI 3522-50 LCR Hi-tester device. Figure (1) shows HIOKI 3522-50 LCR Hi-tester device for measuring characterization of nanocomposite insulation industrial materials. 3. Preparation of Nanocomposites and Characterization The industrial materials studied here are high density polyethylene which has been formulated utilizing variant concentrations of nanoparticles of clay and fumed silica. High density polyethylene nanocomposites have been prepared and fabricated by using recent nanotechnology procedures and devices for melting pure high density polyethylene grains, mixing and penetrating nanoparticles inside the base matrix HDPE by modern ultrasonic devices. Most of all nanocomposite materials are commercial and available already in the manufacturing of high-voltage (HV) industrial products and their properties detailed in Tab. 1. Tab.1: Electric and Dielectric Properties of Pure and Nanocomposite Materials Materials Dielectric Constant at 1kHz Resistivity (Ω.m) Pure HDPE 2.3 1015 HDPE + 1wt% clay 2.23 1016 HDPE + 5wt% clay 1.99 1016-1019 HDPE + 10wt% clay 1.76 1019-1021 HDPE + 1wt% SiO2 2.32 1014 HDPE + 5wt% SiO2 2.39 1014-1012 HDPE + 10wt% SiO2 2.49 1012-1010 (a) Clay/HDPE (b) SiO2/HDPE Fig. 2: Fig. 2 SEM images for high density polyethylene nanocomposites SEM images illustrate penetration of nanoparticles in polymeric nanocomposites; thus, Fig. 2 shows SEM images that illustrate the penetration of cost-fewer nanoparticles in high density polyethylene nanocomposites. It has flakes like morphology with high surface area. Also, it illustrates that the nanoparticles are uniformly dispersed in the polymer matrix. Fig. 2: HIOKI 3522-50 LCR Hi-tester device. c 2017 ADVANCES IN ELECTRICAL AND ELECTRONIC ENGINEERING 56
ELECTRICAL MATERIALS AND EQUIPMENT VOLUME: 15 |NUMBER: 1 |2017 |MARCH Tab. 1: Electric and dielectric properties of pure and nanocomposite materials. Characteristics materials Dielectric constant Resistivity (ω·m) LDPE HDPE LDPE HDPE PurePure 2.3 2.3 1014 1015 1 wt.%Clay 2.23 2.23 1015 1016 5 wt.%Clay 1.99 1.99 1015 −1018 1016 −1019 10 wt.%Clay 1.76 1.76 1018 −1020 1019 −1021 1 wt.%SiO22.32 2.32 1013 1014 5 wt.%SiO22.39 2.39 1013 −1011 1014 −1012 10 wt.%SiO22.49 2.49 1011 −1091012 −1010 3. Results and Discussion Dielectric Spectroscopy is a powerful experimental method to investigate the dynamical electric and dielectric behavior of the polymeric sample through frequency response analysis. This technique is based on the measurement of the resistance, conductance, and susceptance as a function of frequency for a sample sandwiched between pin-plate electrodes. Thus, the conductance and susceptance were measured for all samples as a function of frequency up to 1 kHz under variant temperatures of (20 ◦C and 60 ◦C). 3.1. Measurements on LDPE Nanocomposites Films 1) Effect of Nanoparticles on Conductance Property Figure 3 depicts the conductance of clay/LDPE nanocomposites films that decreases with increasing concentration of clay nanoparticles in the nanocomposites up to 5 wt.%at room temperature (20 ◦C). However, at high temperature (60 ◦C), the conductance performance of clay/LDPE nanocomposites films is reversed within the same concentration range of nanoparticles. 0 100 200 300 400 500 600 700 800 900 1000 0 0.2 0.4 0.6 0.8 1x 10−7 Frequecny (Hz) Conductance (Mho) LDPE Pure LDPE +1 % Clay, 20 °C LDPE +5 % Clay, 20 °C LDPE +1 % Clay, 60 °C LDPE +5 % Clay, 60 °C Fig. 3: Measured conductance of clay/LDPE nanocomposite films. Therefore, increasing temperature of nanocomposites materials changes temperature degrees of nanoparticles that are changing the electric conductance behavior against normal conditions. On the other hand, Fig. 4 shows the conductance of SiO2/LDPE nanocomposites films as a function of frequency. Note that the measured conductance decreases with increasing concentration of fumed silica nanoparticles up to 1 wt.% but it increases with increasing concentration of fumed silica nanoparticles up to 5 wt.%without reaching to values of low-density polyethylene. 0 100 200 300 400 500 600 700 800 900 1000 0 0.2 0.4 0.6 0.8 1x 10−7 Frequecny (Hz) Conductance (Mho) LDPE Pure LDPE +1 % FS, 20 °C LDPE +5 % FS, 20 °C LDPE +1 % FS, 60 °C LDPE +5 % FS, 60 °C Fig. 4: Measured conductance of SiO2/LDPE nanocomposite films. Under high temperature (60 ◦C), the measured conductance of fumed silica/LDPE nanocomposites films increases with increasing concentration of fumed silica nanoparticles in the nanocomposites up to 1 wt.%, then, it decreases with increasing percentage of fumed silica nanoparticles in the nanocomposites up to 5 wt.%. Therefore, there is no stability in conductance property behavior for using fumed silica nanoparticles in low-density polyethylene that can reverse conductance property behavior under high temperature (60 ◦C). 2) Effect of Nanoparticles on Electric Susceptance Property Figure 5 and Fig. 6 show the results of the measurements of susceptance as a function of frequency for clay/LDPE, and SiO2/LDPE nanocomposites films samples under varying thermal temperatures. Note that, Fig. 5 shows that the susceptance of clay/LDPE nanocomposites films increases with the increasing concentration of clay nanoparticles in the nanocomposites up to 5 wt.%under varying thermal conditions (low and high). However, Fig. 6 shows the measured suscepc 2017 ADVANCES IN ELECTRICAL AND ELECTRONIC ENGINEERING 57
ELECTRICAL MATERIALS AND EQUIPMENT VOLUME: 15 |NUMBER: 1 |2017 |MARCH 0 100 200 300 400 500 600 700 800 900 1000 0 0.2 0.4 0.6 0.8 1 1.2 x 10−7 Frequecny (Hz) Suscptance (Mho) LDPE Pure LDPE +1 % Clay, 20 °C LDPE +5 % Clay, 20 °C LDPE +1 % Clay, 60 °C LDPE +5 % Clay, 60 °C Fig. 5: Measured susceptance of cay/LDPE nanocomposite films. 0 100 200 300 400 500 600 700 800 900 1000 0 0.2 0.4 0.6 0.8 1 1.2 x 10−7 Frequecny (Hz) Suscptance (Mho) LDPE Pure LDPE +1 % FS, 20 °C LDPE +5 % FS, 20 °C LDPE +1 % FS, 60 °C LDPE +5 % FS, 60 °C Fig. 6: Measured susceptance of SiO2/LDPE nanocomposite films. tance of SiO2/LDPE nanocomposites films that display the same performance of conductance with increasing fumed silica nanoparticles in low-density polyethylene under varying thermal conditions (low and high). Therefore, rising temperature of nanocomposites materials changes the temperature of nanoparticles that is changing the electric behavior against the normal conditions. Thus, presence of clay nanoparticles in lowdensity polyethylene causes instability of susceptance property behavior in case of high temperatures with respect to room temperature. 3.2. Measurements on HDPE Nanocomposites Films 1) Effect of Nanoparticles on Electric Conductance Property In case of high density polyethylene, Fig. 7 shows the measured conductance of the tested samples of clay/HDPE nanocomposites films as a function of frequency at temperatures of (20 ◦C and 60 ◦C). It is obvious that the measured values of conductance are convergent and increases with the increase of the concentration of clay nanoparticles up to 5 wt.%. However, there is no convergence between the measured values of conductance of high-density polyethylene nanocomposites at high temperature (60 ◦C). On the other hand, Fig. 8 shows the convergence between the measured values of conductance for SiO2/HDPE nanocompos0 200 400 600 800 1000 0 0.2 0.4 0.6 0.8 1x 10−7 Frequecny (Hz) Conductance (Mho) HDPE Pure HDPE +1 % Clay, 20 °C HDPE +5 % Clay, 20 °C HDPE +1 % Clay, 60 °C HDPE +5 % Clay, 60 °C Fig. 7: Measured conductance of clay/HDPE nanocomposite films. 0 100 200 300 400 500 600 700 800 900 1000 0 0.2 0.4 0.6 0.8 1x 10−7 Frequecny (Hz) Conductance (Mho) HDPE Pure HDPE +1 % FS, 20 °C HDPE +5 % FS, 20 °C HDPE +1 % FS, 60 °C HDPE +5 % FS, 60 °C Fig. 8: Measured conductance of SiO2/HDPE nanocomposite films. ites films with increasing concentration of fumed silica nanoparticles up to 5 wt.%at room temperature (20 ◦C). Thus, the measured conductance increases with increasing concentration of fumed silica nanoparticles in the nanocomposites up to 5 wt.%gradually under high thermal conditions. 2) Effect of Nanoparticles on Electric Susceptance Property Figure 9 and Fig. 10 give the results of the measurements of susceptance as a function of frequency for clay/HDPE, and SiO2/HDPE nanocomposites films samples at temperatures of (20 ◦C and 60 ◦C). It is obvious that Fig. 9 focus on increasing susceptance with increasing concentration of clay nanoparticles in the nanocomposites up to 1 wt.%, then, the measured susceptance decreases with increasing concentration of clay nanoparticles up to 5 wt.%. On the other hand, the susceptance of clay/HDPE nanocomposites films increases with increasing concentration of clay nanoparticles up to 5 wt.%at high temperature (60 ◦C). Figure 10 shows the measured susceptance of SiO2/HDPE nanocomposites films samples versus frequency at temperatures of (20 ◦C and 60 ◦C), the susceptance of SiO2/HDPE nanocomposites films increases with increasing concentration of fumed silica nanoparticles in high-density polyethylene nanocomposites up to 1 wt.%at room temperature (20 ◦C), c 2017 ADVANCES IN ELECTRICAL AND ELECTRONIC ENGINEERING 58
ELECTRICAL MATERIALS AND EQUIPMENT VOLUME: 15 |NUMBER: 1 |2017 |MARCH 0 100 200 300 400 500 600 700 800 900 1000 0 0.2 0.4 0.6 0.8 1 1.2 x 10−7 Frequecny (Hz) Suscptance (Mho) HDPE Pure HDPE +1 % FS, 20 °C HDPE +5 % FS, 20 °C HDPE +1 % FS, 60 °C HDPE +5 % FS, 60 °C Fig. 9: Measured susceptance of clay/HDPE nanocomposite films. 0 100 200 300 400 500 600 700 800 900 1000 0 0.2 0.4 0.6 0.8 1x 10−7 Frequecny (Hz) Suscptance (Mho) HDPE Pure HDPE +1 % FS, 20 °C HDPE +5 % FS, 20 °C HDPE +1 % FS, 60 °C HDPE +5 % FS, 60 °C Fig. 10: Measured susceptance of SiO2/HDPE nanocomposite films. but it decreases with increasing concentration of fumed silica nanoparticles up to 5 wt.%at high temperature (60 ◦C). It is clear that the dielectric properties of insulating polymer nanocomposites films have been investigated in the frequency domain from 0.1 Hz to 1 kHz and there is a convergence between the measured values of electric and dielectric polymer properties at room temperature (20 ◦C). 4. Trends of Nanoparticles on Polyethylene Under Thermal Conditions The experimental results focused on effects of nanoparticles on electric characterization under variant thermal conditions. In the beginning, adding fumed silica nanoparticles increased permittivity of the fabricated polyethylene nanocomposites materials, however, adding clay has decreased permittivity of the new nanocomposites materials as shown in Tab. 1. Increasing concentration of clay and fumed silica nanoparticles at room temperature (20 ◦C) affects behavior of conductance and susceptance of polyethylene nanocomposites films and depends on changing the concentration of nanoparticles inside polyethylene materials under low and high frequencies. Types and concentations of nanoparticles display the relationship between electric properties with interfacial medium behavior between the nanoparticles and the polymer matrix in nanocomposite thin films. The aim of adding nanoparticles of clay or fumed silica is controlling on the dielectric strength of commercial polyethylene by using nanotechnology techniques. 5. Conclusion The variation of conductance and susceptance values in polyethylene nanocomposites films can be controlled by changing the types and concentrations of nanoparticles. Increasing concentration of clay nanoparticles in polyethylene decreases the effective permittivity. But, increasing concentration of fumed silica nanoparticles increases effective permittivity of polyethylene nanocomposites films. Presence of special types of nanoparticles inside polyethylene will restrict the chain mobility, then, the result is increasing electric insulation and limiting the generation of mobile charge for the movement of charge carriers in polymer dielectrics. Therefore, the number of charge carriers and applied frequency become dominating factors of the electrical insulation of polyethylene nanocomposites films. New fabricated polyethylene nanocomposites films have high thermal stability at small concentrations of clay or fumed silica nanoparticles. Adding large amounts of these nanoparticles to polyethylene may reverse electric and dielectric behavior characteristics gradually. In addition, rising thermal conditions of nanocomposites materials affect temperatures of nanoparticles and hence change the electric characterization. Acknowledgment The present work was supported by Nanotechnology Research Center at Aswan University that is established by aiding the Science and Technology Development Fund (STDF), Egypt, Grant No: Project ID 505, 2009–2011. References [1] TANIMOTO, G., M. OKASHITA, F. AIDA and Y. FUJIWARA. Temperature dependence of tan δin polyethylene. In: Proceedings of the 3rd International Conference on Properties and Applications of Dielectric Materials. Tokyo: IEEE, 1991, pp. 1068–1071. ISBN 0-87942-568-7. DOI: 10.1109/ICPADM.1991.172259. c 2017 ADVANCES IN ELECTRICAL AND ELECTRONIC ENGINEERING 59
ELECTRICAL MATERIALS AND EQUIPMENT VOLUME: 15 |NUMBER: 1 |2017 |MARCH [2] TOKORO, T., M. NAGAO and M. KOSAKI. High-field dielectric properties and AC dissipation current waveforms of polyethylene film. IEEE Transactions on Dielectrics and Electrical Insulation. 2002, vol. 27, iss. 3, pp. 482–487. ISSN 00189367. DOI: 10.1109/14.142710. [3] ARAOKA, M., H. YONEDA and Y. OHKI. Dielectric properties of new-type polyethylene polymerized using a single-site catalyst. In: IEEE 6th International Conference on Conduction and Breakdown in Solid Dielectrics (ICSD). Vasteras: IEEE, 1998, pp. 493–497. ISBN 0-7803-4237-2. DOI: 10.1109/ICSD.1998.709332. [4] VILCKAS, J. H., L. G. ALBIERO, S. A. CRUZ, M. M. UEKI and M. ZANIN. Study of electrical and mechanical properties of recycled polymer blends. In: International Symposium on Electrical Insulating Materials. Kitakyushu: IEEE, 2005, pp. 683–686. ISBN 4-88686-063-X. DOI: 10.1109/ISEIM.2005.193462. [5] GUO, W. M., B. Z. HAN, H. ZHENG and Z. H. LI. The Effect of Basic Resins on Conductivity Properties of the Polyethylene and Carborundum Composite. In: 8th International Conference on Properties &applications of Dielectric Materials. Bali: IEEE, 2006, pp. 747–750. ISBN 1-4244-01909. DOI: 10.1109/ICPADM.2006.284286. [6] HINATA, K., A. FUJITA, K. TOHYAMA and Y. MURATA. Dielectric Properties of LDPE/MgO Nanocomposite Material under AC High Field. In: 2006 IEEE Conference on Electrical Insulation and Dielectric Phenomena. Kansas City: IEEE, 2006, pp. 683–686. ISBN 4-88686-063-X. DOI: 10.1109/ISEIM.2005.193462. [7] ULZUTUEV, A. N. and N. M. USHAKOV. Investigation of the charge localization processes in the metal polymeric materials based on the low density polyethylene matrix with stabilized nanoparticles. In: 4th International Conference on Advanced Optoelectronics and Lasers (CAOL 2008). Crimea: IEEE, 2008, pp. 435–437. ISBN 978-14244-1973-9. DOI: 10.1109/CAOL.2008.4671988. [8] ISHIMOTO, K., T. TANAKA, Y. OHKI, Y. SEKIGUCHI, Y. MURATA and M. GOSYOWAKI. Comparison of Dielectric Properties of Low-density Polyethylene/MgO Composites with Different Size Fillers. In: Annual Report Conference on Electrical Insulation and Dielectric Phenomena (CEIDP 2008). Quebec: IEEE, 2008, pp. 208–211. ISBN 978-1-4244-25488. DOI: 10.1109/CEIDP.2008.4772819. [9] WANG, X., H. Q. HE, D. M. TU, C. LEI and Q. G. DU. Dielectric Properties and Crystalline Morphology of Low Density Polyethylene Blended with Metallocene Catalyzed Polyethylene. IEEE Transactions on Dielectrics and Electrical Insulation. 2008, vol. 15, iss. 2, pp. 319–326. ISSN 10709878. DOI: 10.1109/TDEI.2008.4483448. [10] GREEN, C. D., A. S. VAUGHAN, G. R. MITCHELL and T. LIU. A Structure property relationships in polyethylene/montmorillonite nanodielectrics. IEEE Transactions on Dielectrics and Electrical Insulation. 2008, vol. 15, iss. 1, pp. 134–143. ISSN 1070-9878. DOI: 10.1109/TDEI.2008.4446744. [11] LYNN, C., A. NEUBER, J. KRILE, J. DICKENS and M. KRISTIANSEN. Electrical conduction in select polymers under shock loading. In: IEEE Pulsed Power Conference. Washington: IEEE, 2009, pp. 171–174. ISBN 978-1-4244-40641. DOI: 10.1109/PPC.2009.5386199. [12] SHAH, K. S., R. C. JAIN, V. SHRINET, A. K. SINGH and D. P. BHARAMBE. High Density Polyethylene (HDPE) Clay Nanocomposite for Dielectric Applications. IEEE Transactions on Dielectrics and Electrical Insulation. 2009, vol. 16, iss. 3, pp. 853–861. ISSN 1070-9878. DOI: 10.1109/TDEI.2009.5128526. [13] SAMI, A., E. DAVID and M. FRECHETTE. Dielectric characterization of high density polyethylene/SiO2nanocomposites. In: IEEE Conference on Electrical Insulation and Dielectric Phenomena. Virginia Beach: IEEE, 2009, pp. 689–692. ISBN 978-1-4244-4557-8. DOI: 10.1109/CEIDP.2009.5377742. [14] BOIS, L., F. CHASSAGNEUX, S. PAROLA, F. BESSUEILLE, Y. BATTIE, N. DESTOUCHES, A. BOUKENTER, N. MONCOFFRE and N. TOULHOAT. Growth of ordered silver nanoparticles in silica film mesostructured with a triblock copolymer PEO–PPO–PEO. Journal of Solid State Chemistry. 2009, vol. 182, iss. 7, pp. 1700–1707. ISSN 00224596. DOI: 10.1016/j.jssc.2009.01.044. [15] DAO, N. L., P. L. LEWIN, I. L. HOSIER and S. G. SWINGLER. A comparison between LDPE and HDPE cable insulation properties following lightning impulse ageing. In: IEEE International Conference on Solid Dielectrics. Potsdam: IEEE, 2010, pp. 1–4. ISBN 978-1-4244-7945-0. DOI: 10.1109/ICSD.2010.5567944. [16] KUZNETSOVA, I. E., B. D. ZAITSEV and A. M. SHIKHABUDINOV. Elastic and viscous properties of nanocomposite films based on low-density polyethylene. IEEE Transactions on Dielectrics and Electrical Insulation. 2010, c 2017 ADVANCES IN ELECTRICAL AND ELECTRONIC ENGINEERING 60
ELECTRICAL MATERIALS AND EQUIPMENT VOLUME: 15 |NUMBER: 1 |2017 |MARCH vol. 57, iss. 9, pp. 2099–2102. ISSN 0885-3010. DOI: 10.1109/TUFFC.2010.1658. [17] SHENGTAO, L., Y. GUILAI, N. FENGYAN, B. SUNA, L. JIANYING and Z. TUO. Investigation on the dielectric properties of nano-titanium dioxide - low density polyethylene composites. In: 10th IEEE International Conference on Solid Dielectrics. Potsdam: IEEE, 2010, pp. 1–4. ISBN 978-1-4244-7943-6. DOI: 10.1109/ICSD.2010.5568106. [18] FANG, P., X. QIU, W. WIRGES, R. GERHARD and L. ZIRKEL. Polyethylene-naphthalate (PEN) ferroelectrets: cellular structure, piezoelectricity and thermal stability. IEEE Transactions on Dielectrics and Electrical Insulation. 2010, vol. 17, iss. 4, pp. 1079–1087. ISSN 10709878. DOI: 10.1109/TDEI.2010.5539678. [19] AMAN, A., M. M. YAACOB, M. A. ALSAEDI and K. A. IBRAHIM. Polymeric composite based on waste material for high voltage outdoor application. International Journal of Electrical Power &Energy Systems. 2013, vol. 45, iss. 1, pp. 346–352. ISSN 0142-0615. DOI: 10.1016/j.ijepes.2012.09.004. [20] DA SILVA, D. A., E. C. M. DA COSTA, J. L. DE FRANCO, M. ANTONIONNI, R. C. DE JESUS, S. R. ABREU, K. LAHTI, L. H. I. MEI and J. PISSOLATO. Reliability of Directly-Molded Polymer Surge Arresters: Degradation by Immersion Test Versus Electrical Performance. International Journal of Electrical Power &Energy Systems. 2013, vol. 53, iss. 1, pp. 488–498. ISSN 0142-0615. DOI: 10.1016/j.ijepes.2013.05.023. [21] SARATHI, R. and R. UMAMAHESWARI. Understanding the Partial Discharge Activity Generated Due to Particle Movement in a Composite Insulation Under AC Voltages. International Journal of Electrical Power &Energy Systems. 2013, vol. 48, iss. 1, pp. 1–9. ISSN 0142-0615. DOI: 10.1016/j.ijepes.2012.11.017. [22] MCCALLEY, J. D. and V. KRISHNAN. A Survey of Transmission Technologies for Planning Long Distance Bulk Transmission Overlay in US. International Journal of Electrical Power &Energy Systems. 2014, vol. 54, iss. 1, pp. 559–568. ISSN 0142-0615. DOI: 10.1016/j.ijepes.2013.08.008. [23] GOUDA, O., A. THABET, Y. A. MOBARAK, M. SAMIR. Nanotechnology Effects on Space Charge Relaxation Measurements for Polyvinyl Chloride Thin Films. International Journal on Electrical Engineering and Informatics. 2014, vol. 6, iss. 1, pp. 1–12. ISSN 2085-5830. DOI: 10.15676/ijeei.2014.6.1.1. [24] THABET, A. Experimental Enhancement for Dielectric Strength of Polyethylene Insulation Materials Using Cost-fewer Nanoparticles. International Journal of Electrical Power &Energy Systems. 2015, vol. 64, no. 1, pp. 469–475. ISSN 01420615. DOI: 10.1016/j.ijepes.2014.06.075. [25] THABET, A. and Y. A. MOBARAK. Experimental Dielectric Measurements for Cost-fewer Polyvinyl Chloride Nanocomposites. International Journal of Electrical and Computer Engineering. 2015, vol. 5, no. 1, pp. 13–22. ISSN 2088-8708. DOI: 10.11591/IJECE.V5I1.6743. [26] THABET, A. Experimental Verification for Improving dielectric strength of polymers by using clay nanoparticles. Advances in Electrical and Electronic Engineering. 2015, vol. 13, no. 2, pp. 182–190. ISSN 1336-1376. DOI: 10.15598/aeee.v13i2.1249. [27] THABET, A. Thermal experimental verification on effects of nanoparticles for enhancing electric and dielectric performance of polyvinyl chloride. Measurement. 2016, vol. 89, no. 1, pp. 28–33. ISSN 0263-2241. DOI: 10.1016/j.measurement.2016.04.002. [28] THABET, A. Theoretical analysis for effects of nanoparticles on dielectric characterization of electrical industrial materials. Electrical Engineering. 2016, vol. 98, iss. 2, pp. 1–7. ISSN 1432-0487. DOI: 10.1007/s00202-016-0375-4. [29] EBNALWALED, A. A. and A. THABET. Controlling the optical constants of PVC nanocomposite films for optoelectronic applications. Synthetic Metals. 2016, vol. 220, iss. 1, pp. 374–383. ISSN 0379-6779. DOI: 10.1016/j.synthmet.2016.07.006. [30] THABET, A and Y. A. MUBARAK. The effect of cost-fewer nanoparticles on the electrical properties of polyvinyl chloride. Electrical Engineering. 2016, vol. 98, iss. 2, pp. 1–7. ISSN 1432-0487. DOI: 10.1007/s00202-016-0392-3. About Authors Ahmed THABET was born in Aswan, Egypt in 1974. He received the B.Sc. (FEE) Electrical Engineering degree in 1997 and M.Sc. (FEE) Electrical Engineering degree in 2002 both from Faculty of Energy Engineering, Aswan, Egypt. Ph.D. degree had been received in Electrical Engineering in 2006 from El-Minia University, Minia, Egypt. He joined with Electrical Power Engineering Group of Faculty of Energy Engineering in Aswan University c 2017 ADVANCES IN ELECTRICAL AND ELECTRONIC ENGINEERING 61
ELECTRICAL MATERIALS AND EQUIPMENT VOLUME: 15 |NUMBER: 1 |2017 |MARCH as a Demonstrator at July 1999, until; he held Associate Professor Position at October 2011 up to date. His research interests lie in the areas of analysis and developing electrical engineering models and applications, investigating novel nano-technology materials via addition nano-scale particles and additives for usage in industrial branch, electromagnetic materials, electroluminescence and the relationship with electrical and thermal ageing of industrial polymers. On 2009, he had been a Principle Investigator of a funded project from Science and Technology Development Fund ”STDF” for developing industrial materials of ac and dc applications by nano-technology techniques. He has been established first Nano-Technology Research Centre in the Upper Egypt. He has many of publications which have been published and under published in national, international journals and conferences and held in Nano-Technology Research Centre website. Youssef MOBARAK was born in Luxor, Egypt in 1971. He received his B.Sc. and M.Sc. degrees in Electrical Engineering from Faculty of Energy Engineering, Aswan University, Egypt, in 1997 and 2001 respectively and Ph.D. from Faculty of Engineering, Cairo University, Egypt, in 2005. He joined Electrical Engineering Department, Faculty of Energy Engineering, Aswan University as a Demonstrator, as an Assistant Lecturer, and as an Assistant Professor during the periods of 1998–2001, 2001–2005, and 2005–2009 respectively. He joined Artificial Complex Systems, Hiroshima University, Japan as a Researcher 2007–2008. Also, he joined King Abdulaziz University, Rabigh, Faculty of Engineering 2010 to present. His research interests are power system planning, operation, and optimization techniques applied to power systems. Also, his research interests are Nanotechnology materials via addition nano-scale particles and additives for usage in industrial field. c 2017 ADVANCES IN ELECTRICAL AND ELECTRONIC ENGINEERING 62