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Protostellar)outflow)shocked)regions:)astrochemical)laboratories) at)our)disposal - THE)CASE)OF)L1157 Juliette)Robuschi –ESO)Garching -March)2025 1 Credit:(ESA/Webb,(NASA(&(CSA,(T.(Ray( (Dublin(Institute(for(Advanced(Studies)( Juliette)Robuschi, Ana)López-Sepulcre,)Cecilia)Ceccarelli, Layal Chahine,)Claudio)Codella,)Linda)Podio
Juliette)Robuschi)–ESO)Garching)-March)2025 2 Before&shock: After&shock:&&&Species)released)in)the)gas)phase)via: Supersonic)jets)(∼150 km/s))impact)matter) surrounding)the)protostar) →creation&of&shocked& regions. Sputtering Shattering(of(the(grains And)/)or ⇒Shocked)regions)=)excellent)astrochemical)laboratories)! Credits :(NASA/JPL-Caltech/UIUC Infrared image(of(L1157(from the(Spitzer Space Telescope Introduction:)Shocked)regions The)source ConclusionsModellingResults
Juliette)Robuschi)–ESO)Garching)-March)2025 3 Introduction:)iCOM)formation The)source ConclusionsModellingResults iCOM ≡(C-bearing) molecule)containing) ≥6)atoms,)with)at) least)one)atom) other)than)C)or)H. e.g.:)C2H5OH& (ethanol),& CH2OHCHO& (glycolaldehyde), NH2CHO) (formamide),)CH3CHO) (acetaldehyde),) CH3COOH)(acetic) acid). iCOMs are)building) blocks)of)more) complex)prebiotic) molecules. Interstellar&Complex&Organic&Molecules IN#THE#GAS-PHASE ON#THE#GRAIN#SURFACES OBSERVATION+ OF iCOMs+FORMED Formation#of#icy#mantles#(at#T∼10#K) Hydrogenation,and,oxidation,of,small, molecules Desorption#in#the#gas-phase Via,thermal,(T,>,100,K),and,nonthermal,processes or,via,shocks Mantle#warming# (+T∼ 20-30+K) Thermal,radical, diffusion Nondiffusive, reactions Surface#reactions Combination,of,radicals Mantle#processing Photolysis,and,radiolysis Gas-phase#reactions Formation,of,more,complex, molecules Adapted(from(a(figure(by(C.(Ceccarelli
Juliette)Robuschi)–ESO)Garching)-March)2025 4 Introduction:)Our)study)case The)source ConclusionsModellingResults Ethanol)– C2H5OH Glycolaldehyde)– CH2OHCHO - Prebiotic)interest. -Formed&on&dust&grains& surfaces. - Prebiotic)interest:)simplest) sugar. -Formation&still&debated. Is&glycolaldehyde&formed&on&dust&grain&surfaces&or&in&the&gas&phase&?
Juliette)Robuschi)–ESO)Garching)-March)2025 5 Introduction:)Our)study)case The)source ConclusionsModellingResults Skouteris+[2018] From(Skouteris+[2018],(after(observations(by(Jørgensen+[2012],( Jaber+[2014],(Coutens+[2015],(Taquet+[2015](and(Lefloch+[2017]. •Combining)radicals)trapped)in)dust)grains)icy)mantles)≠formation)of)more)complex)molecules)(Enrique-Romero+[2016,(2022],( Rimola+[2018]). Ethanol&genealogical& tree Formed(on(dust(grains( surfaces Gas(phase( product Release(in(the(gas( phase Is&glycolaldehyde&formed&on&dust&grain&surfaces&or&in&the&gas&phase&? •Correlation)between)Ethanol/H)and)Glycolaldehyde/H •Theoretical)computations
Juliette)Robuschi)–ESO)Garching)-March)2025 6 Ethanol)abundance)initially)injected)in)the) gas-phase. Time)=)0)⇔Passage)of)the)shock,)injection) of)species)in)the)gas)phase Introduction:)Our)study)case The)source ConclusionsModellingResults If)glycolaldehyde)is)formed)in)the)gas)phase: After)shock)passage): Ethanol)abundance)↘ Glycolaldehyde)abundance)↗
Juliette)Robuschi)–ESO)Garching)-March)2025 7 The)source:)L1157)southern)outflow Introduction ConclusionsModellingResults ∼900)yrs ∼1500)yrs ∼2300)yrs Map)of)the)28SiO)emission)along)L1157&southern&outflow: •Phase)center:)RA(J2000))=)20h39m09s.635,)Dec(J2000))=)+68°01ʹ19ʹʹ.80) •SiO =)shock)tracer)(contours(drawn(with(a(step(of(15𝜎). L1157-mms: •Class)0)protobinary (Tobin+[2022]). •Drives)one)episodic)jet)(Gueth+[1996],(Podio+[2016]).(( •Southern)outflow)rich)in)iCOMs !)(Bachiller+[1995],( Podio+[2014],(Codella+[2017],(Lefloch+[2017]). •3)shocked)regions)in)the)southern)region)(B0,)B1 and)B2)) of)≠and)well-constrained)ages (Podio+[2016]). Allows)to)probe)chemical)evolution)with)time)! Time
Juliette)Robuschi)–ESO)Garching)-March)2025 8 Results:)Identification)and)imaging Introduction ConclusionsModelling The)source Time ∼900)yrs ∼1500)yrs ∼2300)yrs Glycolaldehyde Ethanol Robuschi+[in(prep.]
Juliette)Robuschi)–ESO)Garching)-March)2025 9 Results:)Molecular)abundances Introduction ConclusionsModelling The)source LTE&analysis Assuming((((((Texc =(30(K((((&(((((N(H)(=(2×1021 cm-2 Lefloch+[2017] ØConsistent&so&far:)The glycolaldehyde /)ethanol abundance) ratio)marginally)increases)with)time)→Consistent)with)a)gas) phase)formation)of)glycolaldehyde)triggered)by)the)injection) of)ethanol. ØHowever:)Large)uncertainties)→we)need)to)go)further.) Robuschi+[in(prep.] Ethanol Glycolaldehyde
Juliette)Robuschi)–ESO)Garching)-March)2025 16 Freshly)shocked) material Older)shocked) material •Age)of)B0)? •Excitation)temperature)in)B0)? Appendix:)The)case)of)B0
Juliette)Robuschi)–ESO)Garching)-March)2025 17 →Ran)about)100)models. →The)best)inputs)for)physical)parameters)and)initial) abundances)injected)mostly)agree)with)previous)work)by)our) team)(see(Podio+[2014],(Codella+[2017],(Tinacci+[2023],( Giani+[2023],(López-Sepulcre+[2024]). →Allowed)to)put)constraints)on)most)inputs.) Appendix:)Modelling)inputs
Juliette)Robuschi)–ESO)Garching)-March)2025 18 26/02/2025 Appendix:)Formic)acid)
Juliette)Robuschi)–ESO)Garching)-March)2025 19 Appendix:)Formic)acid’s)column)densities)