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Physicochemical Properties of Camelina Biodiesel and Its Blends

AYDOGAN, Hasan

Abstract

Dataset Description This dataset contains the physicochemical characterization results of biodiesel produced from Camelina sativa oil using the transesterification method.All measurements were performed in an accredited laboratory (TÜBİTAK) in accordance with EN ISO and ASTM standards. The data include the standard fuel quality parameters such as cetane number, kinematic viscosity, sulfur content, flash point, density, water content, oxidation stability, and metallic contents (Na, K, Ca, Mg, P). All parameters were determined for six different fuel blends: B20: 20% biodiesel + 80% diesel B50: 50% biodiesel + 50% diesel B100: 100% biodiesel B20D65E15: 20% biodiesel + 65% diesel + 15% bioethanol B50D35E15: 50% biodiesel + 35% diesel + 15% bioethanol B85D0E15: 85% biodiesel + 15% bioethanol Biodiesel Production Camelina biodiesel was produced via alkaline transesterification using methanol (CH₃OH) and sodium hydroxide (NaOH) as the catalyst. Reaction temperature: 55 °C Catalyst concentration: 3.5 g NaOH per liter of oil Molar ratio: 20% methanol (v/v) relative to oil Stirring rate: 80 L/min for 60 min Separation: Glycerol layer removed after 2 h rest Washing: Distilled water, 1:1 v/v ratio, settled 12 h Drying: 100 °C for 2 h to remove residual water The resulting methyl ester was purified and stored at ambient temperature before blending. Blends of diesel (B0), B20, B50, and B100 were prepared volumetrically. In addition, ethanol-containing blends (B20D65E15, B50D35E15, and B85D0E15) were prepared using bioethanol supplied by Konya Şeker A.Ş. Cite As: Aydoğan, H. (2025). Physicochemical Properties of Camelina Biodiesel and Its Blends [Data set]. Zenodo. https://doi.org/10.5281/zenodo.17329324

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Dataset Title Physicochemical Properties of Camelina Biodiesel and Its Blends 1. Dataset Description This dataset contains the physicochemical characterization results of biodiesel produced from Camelina sativa oil using the transesterification method. All measurements were performed in an accredited laboratory (TÜBİTAK) in accordance with EN ISO and ASTM standards. The data include the standard fuel quality parameters such as cetane number, kinematic viscosity, sulfur content, flash point, density, water content, oxidation stability, and metallic contents (Na, K, Ca, Mg, P). All parameters were determined for six different fuel blends: • B20: 20% biodiesel + 80% diesel • B50: 50% biodiesel + 50% diesel • B100: 100% biodiesel • B20D65E15: 20% biodiesel + 65% diesel + 15% bioethanol • B50D35E15: 50% biodiesel + 35% diesel + 15% bioethanol • B85D0E15: 85% biodiesel + 15% bioethanol 2. Experimental Details 2.1 Biodiesel Production Camelina biodiesel was produced via alkaline transesterification using methanol (CH₃OH) and sodium hydroxide (NaOH) as the catalyst. • Reaction temperature: 55 °C • Catalyst concentration: 3.5 g NaOH per liter of oil • Molar ratio: 20% methanol (v/v) relative to oil • Stirring rate: 80 L/min for 60 min • Separation: Glycerol layer removed after 2 h rest • Washing: Distilled water, 1:1 v/v ratio, settled 12 h • Drying: 100 °C for 2 h to remove residual water The resulting methyl ester was purified and stored at ambient temperature before blending. Blends of diesel (B0), B20, B50, and B100 were prepared volumetrically. In addition, ethanol-containing blends (B20D65E15, B50D35E15, and B85D0E15) were prepared using bioethanol supplied by Konya Şeker A.Ş. 3. Laboratory Analysis All analyses were performed by TÜBİTAK accredited laboratory under Project No. 114M838 using the following standards: Property Method Standard Copper Strip Corrosion Visual comparison EN ISO 2160 Sulfated Ash Gravimetric ISO 3987 Carbon Residue Micro Carbon Residue (MCR) EN ISO 10370 Sulfur Content XRF (UV fluorescence) EN ISO 20846 Cetane Number Engine method EN ISO 5165 Flash Point Pensky–Martens EN ISO 2719 Total Contamination Gravimetric EN 12662 Kinematic Viscosity (40 °C) Capillary viscometer EN ISO 3104 CFPP CFPP apparatus EN 116 Water Content Karl Fischer titration EN ISO 12937 Density (15 °C) Oscillating U-tube EN ISO 12185 Iodine Number Wijs titration EN 14111 Acid Number Titration EN 14104 Oxidation Stability (110 °C) Rancimat EN 14112 Net Calorific Value Bomb calorimeter ASTM D240 Pour Point Pour point apparatus ISO 3016 Group I Metals (Na + K) ICP EN 14108 / EN 14109 Phosphorus ICP EN 14107 Group II Metals (Ca + Mg) ICP EN 14538 4. File Contents File Name Description Analyzed_Parameters.xlsx Full dataset of measured physicochemical properties for each fuel blend. README.txt Dataset description and experimental background. LICENSE.txt Usage and citation license (CC-BY 4.0). 5. Funding Acknowledgment This work was supported by the Scientific and Technological Research Council of Turkey (TÜBİTAK) under Project No: 114M838, conducted under the supervision of Project Principal Investigator (PI): Hasan Aydoğan. Cite: Aydoğan, H. (2025). Physicochemical Properties of Camelina Biodiesel and Its Blends. Zenodo.(https://doi.org/10.5281/zenodo.17329324)